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How do I block certain users from sending e-mails to certain domains?

I have a single site Exchange 5.5 installation and I want to block certain users from sending mails to certain domains. With plain vanilla Exchange, I can only block the domains in IMC. So is there any way to achieve this with simple setup, or do I have to use a third party content-based filtering software? And if so, can you suggest one?
You're going to need to use a third-party product, such as those products listed at http://antivirus.about.com/cs/contentfiltering.

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